The pre-treatment of polyester yarn or fabric is generally based on oil removal, because spinning oil is added to polyester during spinning. So, what oils are generally used in polyester spinning oil?
There are many types of polyester filament oils, including POY and DTY oils, conventional spinning Oil agent, stretch yarn oil agent, textured yarn oil agent and industrial silk oil agent, etc. They can all play a role in bundling, lubrication, reducing friction coefficient, antistatic, etc., but they have their own special functions and adaptability. Even for the same type of filament, due to different processing equipment and post-processing processes, the required oil agent The characteristics should also be different.
Polyester filament oils can be divided into two categories: spinning oils and finished oils. The basic properties of oils are the same, but the performance requirements of spinning oils are high. In finished oils.
Basic properties of oils
1. Smoothness, or lubricity, It is essentially the friction properties of the oil. It is often expressed by the static friction coefficient (μs) and kinetic friction coefficient (μd) between wire and wire (F/F), wire and metal (F/M), and wire and rubber (F/R) after oiling.
Generally speaking, after a better oil agent is applied to the wire, the static friction coefficient of F/F should be appropriately larger, so that the wire has good bundling, good winding shaping, and excellent unwinding properties. There are no special requirements for the dynamic friction coefficient of F/F, but during false twist deformation, if the wire slides, it will easily deform.
It is better that the static friction coefficient of F/M is smaller, and the smaller the kinetic friction coefficient is, the better. This can reduce the friction between the wire and the metal, reduce the hair and broken ends, and reduce the wire pairing. The wear and tear of metal can improve the processing and weaving performance of silk. The static and dynamic friction coefficients of F/R are appropriate. Because during the processing, rubber parts are used to increase the holding force of the wire. If the friction coefficient is too small, it will easily slip. Smoothness is determined by the properties of each component of the oil and has a certain relationship with the lubrication condition.
The lubrication when the oil content is high (0.5% ~ 1.0%) is fluid lubrication. In fluid lubrication, the friction coefficient increases with the increase in oil viscosity and oil content.
The lubrication with the lowest oil content and the smallest friction coefficient is critical lubrication. At high speeds and high contact pressures, maintaining critical lubrication is of great significance. Under critical lubrication conditions, in addition to the viscosity of the oil agent affecting the friction coefficient, the oil film strength (interfacial adsorption force, intermolecular cohesion) also has a great influence on the friction coefficient. The oil film strength is high and the friction coefficient fluctuates little.
2. Antistatic polyester is a good insulator. When rubbed during processing and use, negative static electricity will be generated due to the accumulation of charges.
Static electricity loosens the filament and deteriorates the processability. Therefore, oiled fibers should be antistatic. There are usually three antistatic mechanisms: enhancing the hygroscopicity of fibers; reducing friction; and neutralizing the generated charge. Three mechanisms can work simultaneously. The simplest method to measure the antistatic property of an oil is to measure the specific resistance of the wire after oiling. It can also measure the frictional charge of the wire.
3. Heat resistance For filaments that need to undergo thermal processing (drawing, false twisting, etc.), the heat resistance of the oil used is very important. Oils with poor heat resistance will be damaged at high temperatures. Decompose and the physical properties of the oil change.
The volatilization of oil agents at high temperatures reduces the amount of oiling and pollutes the environment. The tar or oil droplets produced will also affect the operation. The heat resistance of the oil agent can be measured by the volatilization loss method, that is, the oil agent is placed in an oven at 220°C for 8 hours, and its volatilization and decomposition loss are measured.
4. The interface characteristic oil must have certain emulsifying properties. The oil emulsion is required to be stable and the emulsion has low surface tension and low viscosity. Can be evenly adhered to the fiber surface. If the interface characteristics are not good, even if other performance is good, it will not be able to meet the usage requirements.
Use of oil agent
1. Choose oil agent for weaving according to the purpose of the yarn. Silk requires good sizing properties. After sizing, the serous film will not peel off or fall off very little during weaving. This requires good compatibility between the oil agent and the slurry.
The oil agent whose smoothing agent is mineral oil has better sizing properties. Because the viscosity of mineral oil is low, its emulsion oil film is not only compatible with the slurry, but also easy to be redispersed on the surface of the fiber. The oil agent and slurry are replaced, and the oil film can protect the slurry film.
The knitting yarn will be directly put on the machine for warping and weaving, which will cause high-speed friction with the knitting needles. It has high requirements for smoothness, bundling and antistatic properties. The oil used should have low viscosity and The friction coefficient is small and the amount of oil is high.
High temperature resistance should be the main feature of the oil for false twist deformation, and its smoothness should be moderate. If it is too large or too small, it will cause tension changes and make the twist uneven. In addition, the oil agent is required to produce less white powder and adhere evenly. Uneven adhesion affects the dyeing performance of the silk.
There are many brands of oil agents. When a certain oil agent is newly used, it is best to conduct a small test before officially using it in production. Improper use will affect production and product quality.
2. Oil dosage The oil dosage is calculated based on the oil content (OPU) of the yarn. The OPU of conventional spinning and weaving yarns is 0.6% to 0.7%, knitting yarns are 0.7% to 0.9%, and texturing yarns are 0.5% to 0.6%. The amount of oiling in conventional spinning also depends on whether lint and breakage occur during stretching, because some oils with high content will increase the tension of the thread, causing lint and breakage.
High-speed spinning varies with the processing speed of the DTY machine. The higher the processing speed, the lower the OPU should be (see Table 1). If high-speed spinning POY is used to draw drawn yarn, it should be appropriatelyThis trouble is greatest when using fully-filled equipment and when dyeing light and thin fabrics. Some full-fill machines are equipped with back-jet and control valves to control fabric stacking, but since it is impossible to see how the fabric is stacked, tangling is still possible. Reducing tangles can only rely on the experience and responsibility of the operator.
7. Dye spots and color spots:
Cause: dye agglomeration; in the dye bath Oligomers are produced.
Prevention methods: See the relevant content on dye aggregation and oligomer prevention.
8. Fluffing and scratches:
Causes and prevention methods: The nozzle diameter is too small , so that the nozzle pressure is too high, a nozzle with a suitable diameter should be selected according to the weight of the dye, so that the spray pressure is moderate and should not be too large; the cloth speed and the rotation speed of the cloth guide wheel are out of proportion, and the two should be proportional; transporting gray cloth or If the semi-finished product is scratched due to impact, the gray cloth or semi-finished product should be handled with care to prevent impact and scratches; if it is scratched during opening, manual opening should be used.
9. Elongation:
Causes and prevention methods: The cloth capacity is too low, so that The transportation distance of the cloth becomes longer, so that the tension increases, and the cloth capacity should be controlled appropriately; the liquid level of the dye liquor is set too high, thus increasing the resistance between the water and the cloth, and the liquid level should be kept as low as possible.
Repair techniques for common defects
1. Severe uneven dyeing
In this case, the migration property of the dye cannot be used for back and forth repair, and the color must be stripped and then dyed. If it is a light or medium color, it can be dyed into a dark color.
The peeling methods are:
① Oxidation peeling.
Prescription examples: sodium chlorite 2~5g/L, acetic acid (98%) 2~3g/L, methylnaphthalene or chlorobenzene 3~5g/L. The process is: start treatment at 30°C, raise the temperature to 98°C in 30 minutes, boil for 60 minutes, and wash with water. If necessary, use bleaching powder and acetic acid to bleach at boiling temperature.
② Restore and peel color.
Prescription example: caustic soda (flakes) 1g/L, insurance powder 5g/L, chlorobenzene 5g/L. Nonionic surfactant 2g/L. The process is: start treatment at 30°C, raise the temperature to boiling for 30 minutes, boil for 60 minutes, then wash with cold water and hot water. If the stripping is not sufficient, process it again, or use the oxidation stripping method again. Using the above methods may damage the feel of the fabric, so try to avoid it.
2. Wrinkles and mild uneven dyeing:
Wrinkle treatment method: remove the fabric Put it back into the jet dyeing machine, raise the temperature, the temperature should be a few degrees higher than the original dyeing temperature, and then slowly cool down.
For lightly dyed uneven fabrics, the migration property of the dye is generally used for counterdying. The process flow is as follows: start dyeing at 60°C, raise the temperature to 90°C in 15 minutes, and then raise the temperature in 40 minutes. to 130°C, keep warm for 60 minutes, and then cool.
The repair formula is: disperse dye (determined after testing), leveling agent 1~2g/L, and adjust the pH value to 5~6.
When using dyes with poor dye migration, the dyeing temperature should be increased to 135~140°C, but this must be done on the premise that the mechanical properties are acceptable and the hand feel of the fabric is not affected. Leveling agents include carriers (or patching agents).
3. Dyeing oil spots:
① Small batches of local oil spots or dead oil spots Remove. Usually non-ionic detergent, carbon tetrachloride, gasoline and other organic solvents are used, sprayed with a spray gun, washed manually, and then the fabric is washed.
②Removal of large-area oil spots. Use 2~3g/L of degreaser and non-ionic detergent each, and treat it at 100°C for 20 minutes, or use 2~3g/L of degreaser and non-ionic detergent, and 1~2g/L of high-temperature dispersant at 130°C. Process for 20 minutes.
③ Oil spots that are difficult to remove. If the oil spots are serious and difficult to remove, you can consider dyeing them into colors with better coverage such as deep sapphire blue or black. . </p
